|
|
formononetin + reduced_flavodoxin + O2 <=> Calycosin + flavin + H2O
|
1.14.14.88
isoflavone 3'-hydroxylase
|
–
|
K
|
|
BRENDA:
BR29141
KEGG:
R03006
|
|
|
|
Calycosin + reduced_flavodoxin + O2 <=> pseudobaptigenin + flavin + 2 H2O
|
1.14.19.63
pseudobaptigenin synthase
|
–
|
K
|
|
BRENDA:
BR49422
KEGG:
R07745
|
|
|
|
Calycosin <=> rotenone
|
not assigned
|
–
|
K
|
|
KEGG:
R07744
|
|
|
|
UDP-glucose + Calycosin <=> calycosin_7-O-glucoside + UDP + H+
|
2.4.1
|
–
|
M
|
|
MetaCyc:
RXN-16373
|
|
|
|
formononetin + O2 + reduced_[NADPH-hemoprotein_reductase] <=> Calycosin + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14.88
isoflavone 3'-hydroxylase
|
–
|
M
|
|
MetaCyc:
RXN-3762
|
|
|
|
Calycosin + reduced_[NADPH-hemoprotein_reductase] + O2 <=> pseudobaptigenin + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.19.63
pseudobaptigenin synthase
|
–
|
M
|
|
MetaCyc:
RXN-3763
|
|
|
|
S-adenosyl-L-methionine + Calycosin <=> S-adenosyl-L-homocysteine + 7-hydroxy-4''5''-dimethoxyisoflavone + H+
|
2.1.1
|
–
|
M
|
|
MetaCyc:
RXN-9052
|
|
|
|
S-adenosyl-L-methionine + Calycosin <=> 2,7-dihydroxy-4,5''-dimethoxyisoflavone + S-adenosyl-L-homocysteine
|
not assigned
|
–
|
M
|
|
MetaCyc:
RXN-9054
|
|
|
|
O2 + formononetin + H+ + NADPH <=> NADP+ + H2O + Calycosin
|
1.14.14.88
isoflavone 3'-hydroxylase
|
–
|
|
|
SABIO-RK:
2858
|
|